4f-LUMINESCENCE OF LANTHANIDE IONS IN REGIOISOMERIC CORROLE COMPLEXES

Autor: Nikolay N. Semenishyn, Mariia Rusakova, S. S. Smola, Natalia V. Rusakova
Rok vydání: 2021
Předmět:
Zdroj: Ukrainian Chemistry Journal. 87:35-44
ISSN: 2708-129X
2708-1281
DOI: 10.33609/2708-129x.87.09.2021.35-44
Popis: Isomeric ditopic corroles and complexes of Yb (III), Nd (III) and Er (III) based on them were synthesized and corrole-photosensitized 4f-luminescence in near infrared region was revealed. The structure of isomeric complexes allows adjusting the distance between the corrole core and lanthanide ion. The obtained results show that the sensitization mechanism changes drastically for both different lanthanides and isomeric forms.
Databáze: OpenAIRE