On the Radial Dependence of the Fluorescence‐Quenching Interaction between Rare‐Earth Ions

Autor:	M. Kestigian, W. W. Holloway
Rok vydání:	1965
Předmět:	Dipole Valence (chemistry) Quenching (fluorescence) Chemistry Energy transfer Rare earth ions General Physics and Astronomy Physical and Theoretical Chemistry Atomic physics Photochemistry Chemical reaction Fluorescence Ion
Zdroj:	The Journal of Chemical Physics. 43:147-149
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1696443
Popis:	The radial dependence of the quenching interaction between rare‐earth ions has been studied through observation of the Tb3+ fluorescence lifetime in samples of Gd1–2cTbcHocCl3·6H2O. The probability for a quenching interaction, PInt, has been determined to be PInt∝c2∝1/r6. On the basis of the ``resonance'' transfer of energy, such a radial dependence implies a dipole—dipole interaction. Other experiments are discussed in which identical results are obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d1a58d4c032213669acc7978cd84c556 https://doi.org/10.1063/1.1696443 Zobrazit plný text záznamu