Synthesis of 5,10,11,12,17,22,23,24-octahydrotetrabenzo[a,d,i,l]cyclohexadecene derivatives

Autor:	Roger N. Renaud, John W. Bovenkamp
Rok vydání:	1976
Předmět:	chemistry.chemical_compound chemistry Organic Chemistry Diphenylmethane General Chemistry Combinatorial chemistry Catalysis
Zdroj:	Canadian Journal of Chemistry. 54:3548-3552
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v76-510
Popis:	The reaction between 2,2′-bis(bromomethyl)diphenylmethane and diethyl sodiomalonate gives mainly 11,11,23,23-tetracarboethoxy-5,10,11,12,17,22,23,24-octahydrotetrabenzo[a,d,i,l]-cyclohexadecene together with some polymeric compounds. No eight-membered ring products were detected. Starting from the tetracarboethoxy compound described above, the syntheses of a series of di- and tetrasubstituted tetrabenzo[a,d,i,l]cyclohexadecenes are described.
Databáze:	OpenAIRE
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