Debromination of α-Bromoketones and vic-Dibromides Using a NaI/Na2SO3System

Autor:	Yu Mi Chang, Seung Hwan Lee, Cheol Min Yoon
Rok vydání:	2004
Předmět:	Sodium dithionite chemistry.chemical_compound Chemistry Bromide Sodium iodide Halogenation Regioselectivity Sulfuric acid General Chemistry Stoichiometry Nuclear chemistry
Zdroj:	Bulletin of the Korean Chemical Society. 25:1723-1725
ISSN:	0253-2964
DOI:	10.5012/bkcs.2004.25.11.1723
Popis:	Excess amount of sodium iodide in the absence ofany other additives or along with other carbonyl activatingadditive such as sulfuric acid, chlorotrimethylsilane havebeen employed for the reduction of α-haloketones. Recently,stoichiometric amount of HBr as bromide source has beenreported for regioselective bromination of α-haloketones inthe presence of stoichiometric amount of sodium dithionite(Na
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d18afc2db3d9d5940944ca78db54db59 https://doi.org/10.5012/bkcs.2004.25.11.1723 Zobrazit plný text záznamu