X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes
| Autor: | V. I. Ovcharenko, E. Yu. Fursova, A. D. Fedorenko, L. N. Mazalov, S. A. Lavrukhina, Alexander V. Kalinkin |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Spin states
010405 organic chemistry X-ray chemistry.chemical_element Manganese Electronic structure 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray photoelectron spectroscopy Materials Chemistry Emission spectrum Isonicotinamide Physical and Theoretical Chemistry Tetrahydrofuran |
| Zdroj: | Journal of Structural Chemistry. 58:1166-1172 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1134/s0022476617060142 |
| Popis: | The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|