Electron energy loss spectroscopy of the outer valence shells of acetonitrile and methyl isocyanide
| Autor: | Jacques E. Collin, J. Delwiche, F. Edard, M. Gochel-Dupuis, M J Hubin-Franskin, M. Tronc |
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| Rok vydání: | 1990 |
| Předmět: |
Valence (chemistry)
Methyl isocyanide Electron energy loss spectroscopy General Chemistry Biochemistry Electron spectroscopy Catalysis Spectral line chemistry.chemical_compound symbols.namesake Colloid and Surface Chemistry chemistry Computer Science::Systems and Control Excited state Ionization Rydberg formula symbols Atomic physics |
| Zdroj: | Journal of the American Chemical Society. 112:5425-5431 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja00170a005 |
| Popis: | Valence-shell electronic excitation of acetonitrile and methyl isocyanide has been measured by electron energy loss spectroscopy at 20-, 25-, and 70-eV impact energies. The acetonitrile spectra are discussed in terms of valence-state excitation in the 5-9.5-eV region and Rydberg series converging to the first and to the second ionization limits for the 9.5-12-eV energy loss range. For some of these transitions new assignments are proposed. The relative differential cross sections for the most intense Rydberg transitions have been measured as a function of the scattering angle (6-90{degree}). They lead to a discussion of the symmetry of the excited orbitals. The spectrum of methyl isocyanide has been recorded in the 6-13-eV region at 25 eV and 2{degree}. |
| Databáze: | OpenAIRE |
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