A New Picket-Fence Porphyrin Precursor. Synthesis and Atropisomerism of Free Base and Zinc Complex of meso-Tetra(o-methoxycarbonylphenyl)porphyrin
| Autor: | Tsutomu Fujimoto, Norikazu Nishino, Hideki Umekawa |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
inorganic chemicals
Atropisomer biology Stereochemistry fungi Kinetics chemistry.chemical_element Free base General Chemistry Zinc biology.organism_classification Porphyrin carbohydrates (lipids) chemistry.chemical_compound chemistry Porphyrin Precursor Polymer chemistry polycyclic compounds Via fence Tetra heterocyclic compounds |
| Zdroj: | Chemistry Letters. :37-40 |
| ISSN: | 1348-0715 0366-7022 |
| DOI: | 10.1246/cl.1992.37 |
| Popis: | A new picket-fence porphyrin precursor with carboxy terminal groups has been prepared. Four atropisomers of meso-tetra(o-methoxycarbonylphenyl)porphyrin have been separated by chromatography. The conformational stability of the αααα-isomer was examined to the prolonged heating for both free base and zinc complex. The usefulness of meso-tetra(o-carbonylphenyl)porphyrin appeared to be not at all inferior to well-known meso-tetra(o-aminophenyl)porphyrin |
| Databáze: | OpenAIRE |
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