Synthesis, properties, and structure of tetrazoles: Certain achievements and prospects

Autor: Pavel N. Gaponik, Sergei V. Voitekhovich, Oleg A. Ivashkevich
Rok vydání: 2013
Předmět:
Zdroj: Russian Journal of Organic Chemistry. 49:635-654
ISSN: 1608-3393
1070-4280
Popis: The review generalizes and systematizes the results of research on the synthesis and properties of tetrazole derivatives obtained in the Belarusian State University within the last decade. The main attention is fixed on important directions in the tetrazole synthesis: the acid-catalyzed N-alkylation, the reactions of primary amines with triethyl orthoformate and sodium azide followed by the heterocyclization of imidoyl azides, and on the transformation of the obtained 1-aryltetrazoles into 1-aryl-5-aminotetrazoles. The results of quantum-chemical and X-ray investigations as well as aspects of the practical application of tetrazoles are reviewed.
Databáze: OpenAIRE