The preparation and crystal structure of the 1 : 2 adduct of phosphorus trifluoride oxide and antimony pentafluoride

Autor:	Khalaf I. Khallow, Anthony J. Edwards
Rok vydání:	1984
Předmět:	Chemistry Inorganic chemistry chemistry.chemical_element Antimony pentafluoride General Chemistry Phosphorus trifluoride Crystal structure Adduct chemistry.chemical_compound Crystallography Antimony X-ray crystallography Diffractometer Monoclinic crystal system
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :2541
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9840002541
Popis:	The structure of the title adduct has been determined by the heavy-atom method from 2 140 reflections, measured with a diffractometer, and refined by full-matrix least-squares methods to R 0.041. Crystals are monoclinic, space group P21/c, with unit-cell dimensions a= 7.318(2), b= 14.725(4), c= 10.377(10)A, β= 97.73(5)°, and Z= 4. The solid adduct exists as a monomer, with a tetrahedrally co-ordinated phosphorus atom linked through a bridging oxygen atom to complete the octahedral co-ordination of one antimony atom in the Sb2F10 unit.
Databáze:	OpenAIRE
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