Synthesis of macrocyclic chromotropic acid-based sulfonamides; their complexation properties and an unexpected photochemical reaction

Autor:	Louise N. Dawe, Hisham Fathy Sleem, Paris E. Georghiou
Rok vydání:	2013
Předmět:	chemistry.chemical_compound chemistry Reagent Organic Chemistry Drug Discovery Formaldehyde Halide Photochemistry Chromotropic acid Biochemistry
Zdroj:	Tetrahedron Letters. 54:3444-3448
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2013.04.081
Popis:	Chromotropic acid (CTA), a dihydroxynaphthalenedisulfonic acid is a reagent that is widely used for dyestuff manufacture, as a chromogen-forming reagent for the analysis of formaldehyde and as an intermediate for azo derivatives used as analytical reagents. The synthesis of two new CTA-based macrocyclic tetra-sulfonamides 7 and 7a and their corresponding bis-sulfonamides 10 and 10a and their complexation properties toward tetra-n-butylammonium halides were studied. The X-ray structure of 10a was determined and it provided key evidence for an unexpected photochemical reaction that the tetra-sulfonamides underwent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d134b279b6ebb00560f953d6c18d4b6b https://doi.org/10.1016/j.tetlet.2013.04.081 Zobrazit plný text záznamu Full Text from ScienceDirect