Catalytic artificial nitroalkane oxidases – a way towards organocatalytic umpolung

Autor: Adam Pokluda, Ekaterina Zubova, Josef Chudoba, Martin Krupička, Radek Cibulka
Rok vydání: 2023
Předmět:
Zdroj: Organic & Biomolecular Chemistry. 21:2768-2774
ISSN: 1477-0539
1477-0520
DOI: 10.1039/d3ob00101f
Popis: Artificial nitroalkane oxidases based on catalytic amounts of flavins enable nitroalkane umpolung resulting in β-nitroalcohols. Two alternative pathways via flavin-5-iminium species are possible.
Databáze: OpenAIRE