Catalytic artificial nitroalkane oxidases – a way towards organocatalytic umpolung
Autor: | Adam Pokluda, Ekaterina Zubova, Josef Chudoba, Martin Krupička, Radek Cibulka |
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Rok vydání: | 2023 |
Předmět: | |
Zdroj: | Organic & Biomolecular Chemistry. 21:2768-2774 |
ISSN: | 1477-0539 1477-0520 |
DOI: | 10.1039/d3ob00101f |
Popis: | Artificial nitroalkane oxidases based on catalytic amounts of flavins enable nitroalkane umpolung resulting in β-nitroalcohols. Two alternative pathways via flavin-5-iminium species are possible. |
Databáze: | OpenAIRE |
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