Magnetic Activated Carbon Derived from Biomass Waste by Concurrent Synthesis: Efficient Adsorbent for Toxic Dyes
| Autor: | Vitor C. Almeida, Tewodros Asefa, Taís L. Silva, André L. Cazetta, Osvaldo Pezoti, Karen C. Bedin, Andrea Paesano Junior |
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| Rok vydání: | 2016 |
| Předmět: |
Materials science
General Chemical Engineering Maghemite 02 engineering and technology engineering.material 010402 general chemistry 01 natural sciences chemistry.chemical_compound Adsorption medicine Environmental Chemistry Organic chemistry Point of zero charge Magnetite Renewable Energy Sustainability and the Environment Carbonization General Chemistry Microporous material Hematite 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry Chemical engineering visual_art engineering visual_art.visual_art_medium 0210 nano-technology Activated carbon medicine.drug |
| Zdroj: | ACS Sustainable Chemistry & Engineering. 4:1058-1068 |
| ISSN: | 2168-0485 |
| DOI: | 10.1021/acssuschemeng.5b01141 |
| Popis: | The development of advanced carbon nanomaterials that can efficiently extract pollutants from solutions is of great interest for environmental remediation and human safety. Herein we report the synthesis of magnetic activated carbons via simultaneous activation and magnetization processes using carbonized biomass waste from coconut shells (Cb’s) and FeCl3·6H2O as precursor. We also show the ability of the materials to efficiently extract toxic organic dyes from solutions and their ease of separation and recovery from the solutions using a simple bar magnet. Textural characterization shows that the materials are microporous. Further analyses of the deconvoluted XPS spectra and X-ray diffraction patterns reveal that the materials possess magnetite, maghemite and hematite. SEM and TEM images show that an increase in the ratio of FeCl3·6H2O:Cb leads to an increase in the material’s magnetic properties. The point of zero charge (pHpzc) indicates that the materials have acidic characteristics. Adsorption kineti... |
| Databáze: | OpenAIRE |
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