Naked eye detection of cyanide in water with CoII bis(terpyridine) complexes
| Autor: | Indrani Bhowmick, Tarkeshwar Gupta, Robert F. Higgins, David J. Boston, Matthew P. Shores, Christina M. Klug |
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| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Cyanide Metals and Alloys 010402 general chemistry Condensed Matter Physics Photochemistry 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Materials Chemistry Naked eye Electrical and Electronic Engineering Terpyridine Instrumentation Single crystal Cyanide anion |
| Zdroj: | Sensors and Actuators B: Chemical. 235:325-329 |
| ISSN: | 0925-4005 |
| DOI: | 10.1016/j.snb.2016.05.053 |
| Popis: | Herein, we report for the first time CoII bis(terpyridine) complexes as instant ‘naked eye’ colorimetric detectors of cyanide (CN−) in micromolar concentrations in polar solvents, including water, following the formation of the corresponding CoIII tricyanide complex. The new CoIII tricyanide complex [CoIII(4-pyridyl-terpyridine)(CN)3] is characterized by single crystal XRD diffraction. The quanitative detection of cyanide is monitored by UV–vis spectroscopic method and the selectivety of CoII bis(terpyridine) complexes to the cyanide anion is shown via addition of other anions. |
| Databáze: | OpenAIRE |
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