ChemInform Abstract: Substituent Effects on the Amination of Racemic Allyl Carbonates Using Commercially Available Chiral Rhodium Catalysts

Autor:	Ronald L. Blankespoor, Brian Samas, Chase Hulderman, Derek Vrieze, Kurt M. Van Allsburg, Timothy L. Atallah, Philip Homan
Rok vydání:	2014
Předmět:	chemistry.chemical_compound chemistry Substituent Organic chemistry chemistry.chemical_element General Medicine Amination Catalysis Rhodium
Zdroj:	ChemInform. 45
ISSN:	0931-7597
Popis:	In the presence of commercially available chiral rhodium catalysts, a competitive benzylamination of racemic allyl carbonates, substituted with p-X-Ph groups, shows that the reaction proceeds faster with substituents (X) that are more electron-withdrawing. Mechanistic implications of these results are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d1191d94dc0b0368ac868b0d11cb5e44 https://doi.org/10.1002/chin.201407041 Zobrazit plný text záznamu Plný text