Transition metal–carbon bonds. Part XXI. Methyl derivatives of platinum(II) and platinum(IV) containing dimethylphenylarsine as ligand

Autor:	B. L. Shaw, J. D. Ruddick
Rok vydání:	1969
Předmět:	Ligand Inorganic chemistry chemistry.chemical_element Resonance (chemistry) Spectral line Inorganic Chemistry Dipole Crystallography chemistry Transition metal Halogen Physical and Theoretical Chemistry Platinum Carbon
Zdroj:	J. Chem. Soc. A. :2964-2969
ISSN:	0022-4944
Popis:	Methylplatinum(II) complexes of the types cis-[PtMe2(AsMe2Ph)2] and trans-[PtXMe(AsMe2Ph)2](X = halogen), and methylplatinum(IV) complexes of the type [PtX4–nMen(AsMe2Ph)2](X = halogen, n= 1–4) are described. The stereochemistries follow from the methyl resonance patterns in the n.m.r. spectra and are confirmed by dipole moment and i.r. spectral measurements. Values of δ(Me) for the platinum-bonded methyl groups, ν(Pt–C), ν(Pt–Cl), τ(Me) and J(Pt–H) are given and discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d10e869790922515a9f0d5fbd82967ec https://doi.org/10.1039/j19690002964 Zobrazit plný text záznamu