Cation–Cation Interaction in Complexes of Np(V) Benzoate and Salicylate with N-Containing Molecular Ligands
Autor: | I. A. Charushnikova, N. N. Krot, V. P. Perminov |
---|---|
Rok vydání: | 2020 |
Předmět: | |
Zdroj: | Radiochemistry. 62:9-17 |
ISSN: | 1608-3288 1066-3622 |
DOI: | 10.1134/s1066362220010026 |
Popis: | The hydrothermal method was used to obtain two new compounds of Np(V): benzoate [(NpO2)3(py) (C7H5O2)3(H2O)2] (1) and salicylate [(NpO2)(phen)(HOC7H4O2)] (2), where py = pyridine and phen = 1,10-phenanthroline. An X-ray diffraction analysis of these compounds demonstrated that NpO2+ cations are bound together by cation-cation bonds to form distorted squared networks in compound 1 and zigzag chains in 2. |
Databáze: | OpenAIRE |
Externí odkaz: |