New one-dimensional mixed-valence coordination polymers including an iodine-bridged pentanuclear copper(I) cluster unit

Autor:	Masahiko Maekawa, Haruho Anma, Takashi Okubo, Takayoshi Kuroda-Sowa, Yuuki Nakahashi
Rok vydání:	2014
Předmět:	Inorganic Chemistry Diffraction chemistry.chemical_classification Crystallography Valence (chemistry) Chemistry Stereochemistry Materials Chemistry chemistry.chemical_element Polymer Physical and Theoretical Chemistry Iodine Copper
Zdroj:	Polyhedron. 69:103-109
ISSN:	0277-5387
DOI:	10.1016/j.poly.2013.11.026
Popis:	New mixed-valence coordination polymers {[CuI5CuIII5L2(C2H5CN)2]·CHCl3}n (L = piperidine-dithiocarbamate and hexamethyl-dithiocarbamate) with isomorphous infinite one-dimensional (1D) structures were prepared and structurally characterized via X-ray diffraction. These complexes comprised a mononuclear Cu(II) unit, CuIIL2, and a pentanuclear Cu(I) cluster unit, CuI5I5(C2H5CN)2. Impedance measurements demonstrated that these Cu(I)–Cu(II) mixed-valence 1D coordination polymers displayed semiconducting behavior with low conductivities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d0e8265396ff001e8609ef9b01f81705 https://doi.org/10.1016/j.poly.2013.11.026 Zobrazit plný text záznamu Full Text from ScienceDirect