Organic linkage controls the photophysical properties of covalent photosensitizer–polyoxometalate hydrogen evolution dyads
| Autor: | Patrick Endres, Stefanie Schönweiz, Chris Ritchie, Ulrich S. Schubert, Andreas Winter, Salam Maloul, Yusen Luo, Benjamin Dietzek, Maria Wächtler, Carsten Streb |
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| Rok vydání: | 2020 |
| Předmět: |
Renewable Energy
Sustainability and the Environment Energy Engineering and Power Technology Linkage (mechanical) Photochemistry law.invention Catalysis Electron transfer chemistry.chemical_compound Fuel Technology chemistry law Covalent bond Polyoxometalate Reactivity (chemistry) Photosensitizer BODIPY |
| Zdroj: | Sustainable Energy & Fuels. 4:4688-4693 |
| ISSN: | 2398-4902 |
| DOI: | 10.1039/d0se00582g |
| Popis: | Understanding the complex photophysics of covalent photosensitizer–catalyst (PS–CAT) dyads is the basis for advanced structure and reactivity design. Here, we compare the light-induced processes of two PS–CAT hydrogen evolution dyads which differ in the chemical linkage between the Ir photosensitizer and the polyoxometalate catalyst. Variation of the linkage structure results in major changes of the photophysical properties and deactivation pathways which could be one of the factors controlling the catalytic activity. |
| Databáze: | OpenAIRE |
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