Thhorium Metal–Organic Framework Showing Proton Transformation from [NH2(CH3)2]+ to the Carboxyl Group to Enhance Porosity for Selective Adsorption of D2 over H2 and Ammonia Capture
| Autor: | Li Jun Sun, Feng Luo, Hui Ping Zhang, Ya Lin Fan, Han Feng, Li Juan Guo, Meng Jia Yin |
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| Rok vydání: | 2020 |
| Předmět: |
Proton
010405 organic chemistry Chemistry Inorganic chemistry Thorium chemistry.chemical_element General Chemistry 010402 general chemistry Condensed Matter Physics Block (periodic table) 01 natural sciences 0104 chemical sciences Ammonia chemistry.chemical_compound Group (periodic table) Selective adsorption General Materials Science Metal-organic framework Porosity |
| Zdroj: | Crystal Growth & Design. 20:3605-3610 |
| ISSN: | 1528-7505 1528-7483 |
| Popis: | In this work, we report a novel thorium metal–organic framework, [NH2(CH3)][Th2(H2O)2(L)3] (namely, ECUT-36, H3L = 4,4′,4′′-nitrilotribenzoic acid), built on a new Th2 building block, showing a 3,9... |
| Databáze: | OpenAIRE |
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