Simple Method for Technetium Removal from Aqueous Solutions

Autor: William D. Bostick, G. D. Del Cul
Rok vydání: 1995
Předmět:
Zdroj: Nuclear Technology. 109:161-162
ISSN: 1943-7471
0029-5450
DOI: 10.13182/nt95-a35076
Popis: Because of an increasing need for {sup 99}Tc removal from treatment solutions during waste processing and environmental cleanups, several inexpensive sorbents were investigated. Here, Packed-column experiments with iron dust of 40 to 60 mesh (Fisher I-57) showed an excellent uptake of pertechnetate ions from alkaline (pH {approximately} 8.5) high-nitrate (100 to 250 g/l) solutions at flow rates measured in bed volumes (BVs) of between 0.05 and 0.15 BV/min. The columns worked well until they became plugged by rusting after several hundred bed volumes of solution were flowed through (330 to 900 BV). Similar tests using organic ion-exchange resins, such as Dowex SRB-OH and Reillex HP and Reillex HPQ, and the same alkaline high-nitrate solutions showed breakthroughs after 20 to 50 BV were passed.
Databáze: OpenAIRE