Synthesis, characterization and copper incorporation into 5-(4-pyridyl)-10,15,20-triphenylporphyrin

Autor:	George N. Williams, Peter Hambright, Adolphus Lewis, R. F. X. Williams
Rok vydání:	1979
Předmět:	Polarography Polymers and Plastics Chemistry Inorganic chemistry chemistry.chemical_element Free base Porphyrin Copper Catalysis chemistry.chemical_compound Phase (matter) Polymer chemistry Materials Chemistry Reactivity (chemistry) Derivative (chemistry)
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 41:41-44
ISSN:	0022-1902
DOI:	10.1016/0022-1902(79)80390-5
Popis:	5-(4-Pyridyl)-10,15,20-triphenylporphyrin, H 2 TriP, and its water insoluble N-Methyl derivative were synthesized. The PMR and phase selective first and second harmonic polarographic studies were consistent with the proposed structure. In either sodium dodecylsulfate or Triton X-100 detergents, only the free base and di-acid porphyrin forms were present. This was confirmed by a copper incorporation study in SDS, which indicated the absence of a mono-cation, reactivity of only the free base form, and no anion catalysis.
Databáze:	OpenAIRE
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