Synthesis of Polytriarylamines via Microwave-Assisted Palladium-Catalysed Amination
| Autor: | John J. Morrison, I-Wen Shen, Michael L. Turner, Mark C. McCairn |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
Diethylamine
chemistry.chemical_classification Materials science Polymers and Plastics Organic Chemistry chemistry.chemical_element Polymer Combinatorial chemistry Catalysis Organic semiconductor chemistry.chemical_compound Polymerization chemistry Polymer chemistry Materials Chemistry Degradation (geology) Amination Palladium |
| Zdroj: | Macromolecular Rapid Communications. 28:449-455 |
| ISSN: | 1521-3927 1022-1336 |
| DOI: | 10.1002/marc.200600720 |
| Popis: | A new synthetic route to polytriarylamines by microwave-assisted palladium-catalysed amination between 2,4-dimethylaniline and 4,4'-dibromobiphenyl is reported. The use of microwave heating significantly reduces the polymerisation time from days to around five minutes when conducted at 100°C. However, prolonged microwave irradiation (20 min) can cause chain degradation of these polymers. Reactive amino and bromo end-groups can be removed by sequential reaction with 4-bromoanisole and diethylamine to generate polytriarylamines that are suitable for the fabrication of organic electronic devices. |
| Databáze: | OpenAIRE |
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