A Novel Keggin Tungstocobaltate Framework Supported by Copperbipyridyl Complexes: [Cu(I)(2,2' -bipy)2]{[Cu(II)(2,2' -bipy)2]2[HCoW12O40]} · 4H2O

Autor:	Jingquan Sha, Shuxian Li, Li Xin, Fenghua Liu, Youle Qu, Baibin Zhou, Decheng Yu
Rok vydání:	2010
Předmět:	Bipyridine chemistry.chemical_compound Crystallography X-ray photoelectron spectroscopy Chemistry chemistry.chemical_element Molecule General Chemistry Crystal structure Hybrid compound Electrochemistry Copper Hydrothermal circulation
Zdroj:	Zeitschrift für Naturforschung B. 65:1445-1450
ISSN:	1865-7117 0932-0776
Popis:	A new organic-inorganic hybrid compound based on Keggin tungstocobaltate units supported by copper complexes, [Cu(I)(2,2’-bipy)2]{[Cu(II)(2,2’-bipy)2]2[HCoW12O40]} ・ 4H2O (bipy = bipyridine), has been synthesized under hydrothermal conditions and characterized by elemental, IR, TG, and XPS analyses and X-ray single-crystal structure determination. The crystal structure is built up from bi-supported Keggin tungstocobaltate polyoxoanions {[Cu(II)(2,2’-bipy)2]2[HCoW12O40]}−, [Cu(I)(2,2’-bipy)2]+ cations and water molecules. The title compound possesses a 1D tangled helical structure composed of {[Cu(II)(2,2’-bipy)2]2[HCoW12O40]}− polyoxoanions via π・ ・ ・π interactions along the c axis. The electrochemical behavior of the title compound was studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d08a6c3947c2d23061e8cb5613ce666f https://doi.org/10.1515/znb-2010-1206 Zobrazit plný text záznamu