1,1-Dimethyl-1-(trialkoxysilylmethyl)hydrazinium and 1,1-Dimethyl-1-(silatranylmethyl)hydrazinium Halides

Autor: M. S. Sorokin, M. G. Voronkov
Rok vydání: 2005
Předmět:
Zdroj: Russian Journal of General Chemistry. 75:862-866
ISSN: 1608-3350
1070-3632
Popis: Formerly unknown 1,1-dimethyl-1-(trialkoxysilylmethyl)- and 1,1-dimethyl-1-(silatranylmethyl)hydrazinium halides were prepared by reaction of 1,1-dimethylhydrazine with (halomethyl)trialkoxysilanes XCH2Si(OR)3 (X = Cl, I; R=Me, Et) and 1-(halomethyl)silatranes XCH2Si(OCH2CH2)3N (X = Cl, Br). 1,1-Dimethyl-1-(silatranylmethyl)hydrazinium chloride and iodide were also obtained by transetherification of corresponding 1,1-dimethyl-1-(trimethoxysilylmethyl)hydrazinium halides with tris(2-hydroxyethyl)amine.
Databáze: OpenAIRE