Evidence for the fluxionality and structure in solution of intermediates of the type W(CO)4(L) (L = lewis base)

Autor:	Ahmad Moradi-araghi, Donald J. Darensbourg, Gerard R. Dobson
Rok vydání:	1976
Předmět:	Substitution reaction Chemistry Stereochemistry Organic Chemistry Biochemistry Square pyramidal molecular geometry Dissociation (chemistry) Inorganic Chemistry Crystallography Square pyramid Materials Chemistry Amine gas treating Lewis acids and bases Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 116:C17-C20
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)91799-6
Popis:	Evidence based on amine substitution reactions in W(CO)4(tmpa) (tmpa = N,N,N′,N′-tetramethyl-l,3-diaminopropane) and cis-(C5H10NH)(PPh3)W(CO)4 with PPh3 and 13CO indicates (a) that the square pyramidal [W(CO)4PPh3] intermediate arising from amine dissociation is fluxional, and (b) that the intermediate containing PPh3 in the equatorial plane of the square pyramid is thermodynamically more stable than that containing PPh3 in the axial position.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d07a3ced5cbe7b6940414ea07cba03c0 https://doi.org/10.1016/s0022-328x(00)91799-6 Zobrazit plný text záznamu