Investigation of Carbon Supported Nanostructured PtAu Alloy as Electrocatalyst for Direct Borohydride Fuel Cell
| Autor: | Gamze Behmenyar, Tansel Şener, Ç. İyigün Karadağ, F. G. Boyacı San |
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| Rok vydání: | 2015 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element Electrochemistry Electrocatalyst Catalysis Sodium borohydride chemistry.chemical_compound chemistry X-ray photoelectron spectroscopy Direct borohydride fuel cell Bimetallic strip Carbon |
| Zdroj: | Fuel Cells. 15:262-269 |
| ISSN: | 1615-6846 |
| Popis: | Carbon supported bimetallic PtAu electrocatalysts for sodium borohydride electrooxidation are prepared by a modified citrate stabilized NaBH4 reduction process at different pH and temperature values. The physical properties of the materials are characterized by X-ray diffraction spectroscopy, energy dispersive spectrometry, X-ray photoelectron spectroscopy and transmission electron microscopy. Nano sized electrocatalysts have narrow size distributions and are uniformly dispersed on the surface of carbon support. Electrochemical performances of catalysts for sodium borohydride electrooxidation are tested with 25 cm2 single fuel cell. The highest performance is obtained at a peak power density of 161 mW cm−2 with 20 wt. % PtAu/C catalyst of 7.03 nm. Impact of the fuel cell operation parameters including concentration of NaBH4, flow rates of oxidant and fuel, and fuel cell operation temperature are investigated. The best operation parameters are obtained at 1 M NaBH4 concentration, 3 cm3 min−1 NaBH4 flow rate, 0.2 dm3 min−1 oxygen flow rate and 65 °C fuel cell temperature. |
| Databáze: | OpenAIRE |
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