Synthesis of Sterically Hindered Secondary and Tertiary Alkyl(Aryl)Phosphines

Autor:	O. S. Vinogradova, E. A. Neganova, Yu. A. Veits
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Steric effects Chemistry Aryl chemistry.chemical_element Ether General Chemistry Medicinal chemistry Catalysis chemistry.chemical_compound Organic chemistry Phosphine Alkyl Palladium
Zdroj:	Russian Journal of General Chemistry. 75:212-216
ISSN:	1608-3350 1070-3632
DOI:	10.1007/s11176-005-0200-7
Popis:	Cross coupling of silylphosphines with 2-halobenzenecarboxylates or 2-halophenyl ethers, catalyzed with zero-valent palladium complexes can not be used as a procedure for preparing sterically hindered tertiary phosphines. The latter compounds can be successfully prepared by means of phosphorylation of corresponding o-lithiated derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d049624c05ea190d27b126cd1c127479 https://doi.org/10.1007/s11176-005-0200-7 Zobrazit plný text záznamu Plný text ve formátu PDF