| Autor: |
Marty Lail, Paul Mobley, Brian Turk, Laura Douglas, Jonathan E. Peters, Jian-Ping Shen, Jason Scott Norman |
| Rok vydání: |
2014 |
| Předmět: |
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| Zdroj: |
RSC Adv.. 4:45198-45206 |
| ISSN: |
2046-2069 |
| DOI: |
10.1039/c4ra05294c |
| Popis: |
A mechanistic study has been performed to show that a reduced mixed metal oxide derived from tin, iron, and aluminum oxides can remove oxygen from carbon dioxide. Thermogravimetric analysis confirms that reduction of the mixed-metal oxide likely involves the reduction of SnO2and Fe2O3 phases. The reduced mixed-metal oxide can remove oxygen from carbon dioxide and this is shown using isotopically labelled C18O2 and mass spectroscopy. The 18O-labelled mixed-metal oxide can transfer the abstracted oxygen to a different carbonaceous compound, in this case carbon monoxide. Oxygen is readily exchanged in the mixed-metal oxide. Under both oxidizing and reducing conditions 18O is exchanged with unlabelled O resulting in the observation of all isotopomers. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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