(2S,4aR,8aS)-6-Oxoperhydronaphthalene-2-acetic acid: 'conglomerate' crystallization and catemeric hydrogen bonding in a bicyclic η-keto acid

Autor:	Marisa DeVita Dufort, Janish Desai, Roger A. Lalancette, Hugh W. Thompson
Rok vydání:	2007
Předmět:	Bicyclic molecule Stereochemistry Chemistry Hydrogen bond Solid-state General Chemistry Condensed Matter Physics law.invention Crystallography Acetic acid chemistry.chemical_compound law General Materials Science Keto acid Crystallization
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 63:o2753-o2753
ISSN:	1600-5368
Popis:	The title compound, C12H18O3, produces crystals of a single enanti­omer from a racemic solution; these associate in the solid state in a translational acid-to-ketone catemeric mode [O⋯O = 2.7087 (15) A and O—H⋯O = 175 (2)°], producing two screw-related hydrogen-bonded chains. The ring-fusion and side-chain stereochemistry arise during the synthesis from a 4-substituted cyclo­hexa­none.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d029ee4258a098c4d559115422889e5f https://doi.org/10.1107/s1600536807019666 Zobrazit plný text záznamu Plný text ve formátu PDF