Ion Exchange of Layered Alkali Titanates (Na2Ti3O7, K2Ti4O9, and Cs2Ti5O11) with Alkali Halides by the Solid-State Reactions at Room Temperature

Autor:	Thipwipa Sirinakorn, Taya Ko Saothayanun, Makoto Ogawa
Rok vydání:	2020
Předmět:	Chemical substance Ion exchange 010405 organic chemistry Chemistry Diffusion Inorganic chemistry Halide 010402 general chemistry Alkali metal 01 natural sciences Titanate 0104 chemical sciences law.invention Inorganic Chemistry Magazine law Particle size Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 59:4024-4029
ISSN:	1520-510X 0020-1669
DOI:	10.1021/acs.inorgchem.9b03695
Popis:	Ion exchange of layered alkali titanates (Na2Ti3O7, K2Ti4O9, and Cs2Ti5O11) with several alkali metal halides surprisingly proceeded in the solid-state at room temperature. The reaction was governed by thermodynamic parameters and was completed within a shorter time when the titanates with a smaller particle size were employed. On the other hand, the required time for the ion exchange was shorter in the cases of Cs2Ti5O11 than those of K2Ti4O9 irrespective of the particle size of the titanates, suggesting faster diffusion of the interlayer cation in the titanate with lower layer charge density.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d025f90f23e1fd3333ae6f99e3caa53f https://doi.org/10.1021/acs.inorgchem.9b03695 Zobrazit plný text záznamu