ChemInform Abstract: Synthesis of 4-Deoxycarbazomycin B: A Convenient Alternative

Autor:	Bejoy K. Chowdhury, Shailendra Jha
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Aqueous solution Iodide Diphenylamine chemistry.chemical_element General Medicine Potassium carbonate Acetic acid chemistry.chemical_compound Hydrolysis chemistry Bromobenzene Nuclear chemistry Palladium
Zdroj:	ChemInform. 32
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200144235
Popis:	4-Deoxycarbazomycin B(3) was synthesized by condensation of 4-methoxy-2,3-dimethylacetanilide (8) with bromobenzene in presence of cuprous iodide and potassium carbonate, and subsequent hydrolysis with 20% aqueous ethanolic KOH, followed by cyclisation of the resulting substituted diphenylamine (9) with palladium acetate in acetic acid.
Databáze:	OpenAIRE
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