Synthesis and characterization of ruthenium acetate complexes containing triphosphines

Autor:	Devon W. Meek, Guochen Jia, Brian S. Haggerty, Arnold L. Rheingold
Rok vydání:	1992
Předmět:	Chemistry Stereochemistry Infrared spectroscopy chemistry.chemical_element Crystal structure Ruthenium Inorganic Chemistry Crystallography chemistry.chemical_compound X-ray crystallography Molecule Methanol Carboxylate Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 31:900-904
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00031a036
Popis:	A series of ruthenium(II) acetate complexes were synthesized and characterized by 31 P{ 1 H}, 1 H, and 13 C{ 1 H} NMR and IR spectroscopy. Treatment of RuCl 2 (Cyttp) (Cyttp=PhP(CH 2 CH 2 CH 2 P(c-C 6 H 11 ) 2 ) 2 ) with 1 equiv of AgO 2 CMe at room temperature gives mer-RuCl(O 2 CMe)(Cyttp) and with excess NaO 2 CMe in refluxing methanol produces fac-RuCl(O 2 CMe)(Cyttp)
Databáze:	OpenAIRE
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