Tetra-tert-butylethylene: An Elusive Molecule with a Highly Twisted Double Bond. Can It Be Made by Carbene Dimerization?
| Autor: | Horst M. Sulzbach, a,b, a Henry F. Schaefer Iii, Paul von Ragué Schleyer,†,‡ and, a Evan Bolton, c Dieter Lenoir |
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| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Double bond Molecular model Stereochemistry Carbene dimerization Hartree–Fock method General Chemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Chemical bond Computational chemistry Tetra-tert-butylethylene Molecule Stable molecule |
| Zdroj: | Journal of the American Chemical Society. 118:9908-9914 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja960549r |
| Popis: | A theoretical evaluation of tetra-tert-butylethylene (1) at the BLYP/DZd level confirms that it should be a stable molecule with a singlet ground state. The synthesis of 1 from two molecules of di-... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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