Desulfurization of biotin and epibiotin sulfoxides with nickel boride: Analysis of the stereoselectivity through [2H] NMR in a polypeptide liquid crystal

Autor:	Andrée Marquet, Jacques Courtieu, Cécile Canlet, Dominique Florentin, Franck Escalettes
Rok vydání:	1998
Předmět:	inorganic chemicals Chemistry Organic Chemistry technology industry and agriculture Biochemistry Combinatorial chemistry Flue-gas desulfurization chemistry.chemical_compound Biotin Deuterium Liquid crystal Reagent Drug Discovery Organic chemistry Stereoselectivity Nickel boride
Zdroj:	Tetrahedron Letters. 39:7499-7502
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(98)01625-6
Popis:	Reduction of biotin or epibiotin sulfoxides with nickel boride and deuterated reagents affords as major products bideuterated dethiobiotin. Deuterium localisation by [ 2 H] NMR in a chiral liquid crystal allows the analysis of the stereoselectivity of the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cfd4ffbfacd7297d0e6f216d21c9f574 https://doi.org/10.1016/s0040-4039(98)01625-6 Zobrazit plný text záznamu Full Text from ScienceDirect