First-order A1(TO) phonons as evidence of disorder in BaTiO3

Autor: E. Gallego-Lluesma, S. P. S. Porto, J. L. Verble
Rok vydání: 1978
Předmět:
Zdroj: Journal of Raman Spectroscopy. 7:7-9
ISSN: 0377-0486
DOI: 10.1002/jrs.1250070106
Popis: Evidence is presented, based on Raman scattering measurements, that the three modes observed in the A1(TO) phonon spectrum of tetragonal BaTiO3 are first order. These results are interpreted as supporting the order-disorder model of the ferroelectric phase transition.
Databáze: OpenAIRE