Metal–Organic Frameworks of Magnesium Based on 2,5-Dihydroxy-3,6-di-tert-butyl-para-benzoquinone

Autor:	Pavel V. Dorovatovskii, Alexandr V. Piskunov, Ilya A. Yakushev, O. Yu. Trofimova, R. R. Aisin, Irina V. Ershova, A. V. Maleeva
Rok vydání:	2021
Předmět:	Tert butyl Structure analysis Chemistry Magnesium General Chemical Engineering chemistry.chemical_element Thermal stability Para-Benzoquinone Metal-organic framework General Chemistry Crystal structure Medicinal chemistry
Zdroj:	Russian Journal of Coordination Chemistry. 47:610-619
ISSN:	1608-3318 1070-3284
Popis:	New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF]n (I), [Mg(pQ)·2DMAA]n (II), and [Mg(pQ)·2(NMP)]n (III) (pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion) are synthesized by the solvothermal method in different solvents (N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMAA), and N-methyl-2-pyrrolidone (NMP)). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files CCDC nos. 2058147 (I) and 2058148 (II)). The spectral characteristics and thermal stability of the synthesized metal−organic frameworks are studied.
Databáze:	OpenAIRE
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