Homogeneous mono- and bimetallic palladium based catalysts for the carbonylation of allyl chloride

Autor:	Hua Chen, Heng Jiang, Shijian Liao, Xianjun Li, Yun Xu, Daorong Yu
Rok vydání:	1998
Předmět:	Allyl chloride Process Chemistry and Technology Inorganic chemistry chemistry.chemical_element Homogeneous catalysis Catalysis chemistry.chemical_compound chemistry Physical and Theoretical Chemistry TPPTS Selectivity Carbonylation Palladium Nuclear chemistry Carbon monoxide
Zdroj:	Journal of Molecular Catalysis A: Chemical. 130:79-84
ISSN:	1381-1169
DOI:	10.1016/s1381-1169(97)00200-8
Popis:	PdCl2(TPPTS)2 [TPPTS=(m-C6H4SO3Na)3P] is used as catalyst in the carbonylation of allyl chloride. This catalyst exhibits very high activity and selectivity in the dilute alcoholic–aqueous NaOH/toluene medium under atmospheric pressure of carbon monoxide at 40°C. Ethanol plays an important role for increasing the catalytic activity and selectivity of PdCl2(TPPTS)2. The turnover reaches 2.7×104 (mol CO/mol Pd) in 21.5 h when the mole ratio of substrate/catalyst is 3×104. A synergic effect was observed when a second transition metal compound was added to the catalytic system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cfc5d87b068ef84a66ffe751acf7f518 https://doi.org/10.1016/s1381-1169(97)00200-8 Zobrazit plný text záznamu Full Text from ScienceDirect