Development and Morphological Characterization of Novel Polyimide/Metal nano Hybrid Materials

Autor:	Georgiana Bulai, Silviu Gurlui, George Stoian, Iuliana Stoica, M. Strat, Ion Sava, Bogdan Oprisan
Rok vydání:	2019
Předmět:	Metal Materials science Polymers and Plastics Mechanics of Materials visual_art Materials Chemistry visual_art.visual_art_medium Nano hybrid Nanotechnology General Chemistry Polyimide Characterization (materials science)
Zdroj:	Materiale Plastice. 57:94-103
ISSN:	2668-8220 0025-5289
DOI:	10.37358/mp.20.2.5355
Popis:	Two different polyimide structures were synthesized by two-step polycondensation reaction in solution, in the first step using equimolar amounts of one of two aromatic diamine (DDM or MMDA) and one dianhydride (6HDA) in N,N-dimethylacetamide (DMAc) to obtain the poly(amic acids), followed in the second step by thermal imidization. In order to obtain novel polyimide/metal nano hybrid materials, conductive Ni/Cu nanoparticles were embedded on polyimide substrates, using laser ablation technique. The morphology of the resulted thin metal layers was investigated using atomic force microscopy (AFM), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The results highlighted different surface characteristics of the auto-organized metallic/polymer nanoparticles, depending on the chemical structure of the polyimide substrate, the parameters of the laser ablation setup, the deposition time, the type of the metallic target. The obtained features of these polyimide/metal nano hybrid materials can be employed as an indicator of the possibility of using them for potential applications as conductive circuits or substrates for adhesion control.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cfbc31a1ce4e524f4c12bf1959bbf0c8 https://doi.org/10.37358/mp.20.2.5355 Zobrazit plný text záznamu