Intramolecular exciplex formation and complexing behavior of 1-(2-naphthalenecarboxy)-n-(p-substituted benzenecarboxy)oxaalkanes as fluorescent chemosensors for calcium and barium ions
| Autor: | Masahiko Nagaki, Shoei Ito, Hiroaki Kimura, Haruo Kitahara, Jun Kawakami |
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| Rok vydání: | 2004 |
| Předmět: |
Quenching (fluorescence)
Chemistry General Chemical Engineering Metal ions in aqueous solution General Physics and Astronomy General Chemistry Photochemistry Medicinal chemistry Fluorescence Acceptor Fluorescence spectroscopy Metal chemistry.chemical_compound Electron transfer visual_art visual_art.visual_art_medium Acetonitrile |
| Zdroj: | Journal of Photochemistry and Photobiology A: Chemistry. 161:141-149 |
| ISSN: | 1010-6030 |
| DOI: | 10.1016/s1010-6030(03)00283-1 |
| Popis: | 1-(2-Naphthalenecarboxy)- n -( p -substituted benzenecarboxy)oxaalkanes (2NP n X, X=H, Cl, CF 3 , CN; n =5, 6) as fluorescent sensors by exciplex emission for metal ions were synthesized. We investigated the relationship between the substitution effects and the metal ion recognition. Before the metal salts were added, the substitution effect was found. The fluorescence quantum yields ( Φ f ) decrease as the electronegativity of the p -substituent of the acceptor benzoate increases. 2NP n CN ( n =5, 6) with the most negative free energy of electron transfer (Δ G ET ) showed the most efficient quenching and exciplex emission. When Li + , Na + , K + and Mg 2+ were added to the acetonitrile solution of 2NP n X (X=H, Cl, CF 3 , CN; n =5, 6), the shape and intensity of the fluorescence spectra did not change. However, the spectra of all the 2NP n Xs significantly changed with the addition of Ca 2+ and Ba 2+ . Especially, due to the large fluorescent enhancement factor of 2NP n CN ( n =5, 6) for Ca 2+ , they are well-suited for use as a fluorescent chemosensor for Ca 2+ . |
| Databáze: | OpenAIRE |
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