Clusters derived from the hydroboration of decacarbonyldi-.mu.-hydridotriosmium and their derivatives

Autor:	Leh Yeh Hsu, Jeanette A. Krause, Deng Yang Jan, Sheldon G. Shore, David P. Workman
Rok vydání:	1992
Předmět:	Inorganic Chemistry chemistry.chemical_compound Crystallography Hydroboration chemistry Stereochemistry X-ray crystallography Cluster (physics) Carbyne Molecule Crystal structure Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 31:5123-5131
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00050a036
Popis:	Hydroboration of the unsaturated cluster (μ-H) 2 Os 3 (CO) 10 by B 2 H 6 yields (μ-H) 3 Os 3 (CO) 9 (μ 3 -BCO) (I) or [(μ-H) 3 Os 3 (CO) 9 (μ 3 -C-)] 3 (O 3 B 3 O 3 ) (II) is depending upon the conditions chosen. Complex I, is the analogue of a ketenylidene cluster.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cfabaa8ad75bfae960ae4f8cb8582a38 https://doi.org/10.1021/ic00050a036 Zobrazit plný text záznamu