Ionic conductivity of swollen LDPE/poly(4-vinylpyridine) blend
| Autor: | Glaucione Gomes De Barros, Sidnei Luis Andrade da Silva |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
Arrhenius equation
Polymers and Plastics Chemistry Sorption General Chemistry Atmospheric temperature range Conductivity Condensed Matter Physics symbols.namesake Low-density polyethylene Chemical engineering Polymerization Polymer chemistry Materials Chemistry symbols Ionic conductivity Polymer blend |
| Zdroj: | Polymer Bulletin. 47:579-585 |
| ISSN: | 1436-2449 0170-0839 |
| DOI: | 10.1007/s002890200024 |
| Popis: | LDPE/P4VP films synthesized by in situ sorption and thermal polymerization of 4-vinylpyridine, (4VP), were used for conductivity investigations. The conductivities of swollen films varied from 7×10−6 to 1.21×10−3 S.cm−1 at room temperature depending on P4VP mass increase in the host matrix. For the temperature range of 303–333K the conductivity varied from 7×10−6 to 2.66×10−3 S.cm−1. A comparison between Arrhenius and VTF plots for conductivity measurements showed a best fit for temperature dependence according Arrhenius modified equation. The materials are stable for temperatures below 645 K. |
| Databáze: | OpenAIRE |
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