Synthesis and study of thermal stability of 3-nitro-1,2,4-triazole N-nitroxy-and N-azidomethyl derivatives

Autor: I. V. Tselinskii, S. M. Putis, V. V. Tolstyakov, S. F. Mel’nikova
Rok vydání: 2009
Předmět:
Zdroj: Russian Chemical Bulletin. 58:2356-2361
ISSN: 1573-9171
1066-5285
DOI: 10.1007/s11172-009-0327-5
Popis: A method for the preparation of new 3-nitro-1,2,4-triazole derivatives has been suggested based on modification of the N-hydroxymethyl group by nitration and nucleophilic substitution reactions. Thermal stability of 3-nitro-1,2,4-triazole N-nitroxy- and N-azidomethyl derivatives, as well as of dinitrates, 5,5′-dinitro-2,2 ′-bisnitroxymethyl-2 H,2′H-3,3 ′-bi(1,2,4-triazole) and -(nitromethylene)bis(1,2,4-triazole), has been studied.
Databáze: OpenAIRE