Carbonylation of olefins and alcohols with carbon monoxide in presence of catalyst system composed of monovalent copper-carbon monoxide and boron trifluoride-phosphoric acid complexes

Autor:	Ya. T. Éidus, K. G. Ryabova, K. V. Puzitskii, T. N. Myshenkova, S. D. Pirozhkov
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Double bond chemistry.chemical_element General Chemistry Branching (polymer chemistry) Copper Catalysis chemistry.chemical_compound chemistry Polymer chemistry Organic chemistry Carbonylation Phosphoric acid Boron trifluoride Carbon monoxide
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:371-373
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925791
Popis:	Olefins with branching at the double bond, and secondary and tertiary alcohols are carbonylated at atmospheric pressure and 25° in the presence of the catalyst system composed of the Cu(I)-CO and (BF3·H2O)·2(BF3·H3PO4) complexes to giveα,α-dimethylalkanoic acids in 70–94% yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cf90a4a9cef99239e5663afe0c1cec19 https://doi.org/10.1007/bf00925791 Zobrazit plný text záznamu Full text from SpringerLink