Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

Autor:	Kouji Kamata, Yuta Nakai, Atsuko Suzuki, Hiroshi Nakazawa
Rok vydání:	2012
Předmět:	Inorganic Chemistry Olefin fiber chemistry.chemical_compound Chemistry Hydrosilylation Organic Chemistry Polymer chemistry Organic chemistry Physical and Theoretical Chemistry Terpyridine Catalysis
Zdroj:	Organometallics. 31:3825-3828
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om300279t
Popis:	Iron complexes formulated as Fe(terpy)X2 (terpy = 2,2′:6′,2″-terpyridine derivatives; X = Cl, Br) were prepared and their catalytic activities for hydrosilylation of olefin with hydrosilane were examined. Although Fe(terpy)X2 did not show catalytic activity, the treatment of Fe(terpy)X2 with NaHBEt3 caused catalytic activity. The influence of substituents in terpy on the catalytic activity was examined, and it was found that some complexes with an unsymmetrically disubstituted terpy selectively produced 1-silylalkane with quite high catalytic activity. In the reaction of 1-octene with PhSiH3, the double-hydrosilylation product Ph(1-octyl)2SiH was selectively obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cf271f586cfb30ba2da6e0784f6c6b09 https://doi.org/10.1021/om300279t Zobrazit plný text záznamu