Synthesis and Characterization of Soluble Poly(ferrocenylenearylene)s from Condensation of Dilithio Bis(alkylcyclopentadienide)arenes with Iron(II) Halides: A General Route to Conjugated Poly(metallocene)s

Autor:	M. David Curtis, Glen E. Southard and
Rok vydání:	2000
Předmět:	chemistry.chemical_classification Organic Chemistry Condensation Halide Disproportionation Polymer Conjugated system Alkylation Photochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Antiferromagnetism Physical and Theoretical Chemistry Metallocene
Zdroj:	Organometallics. 20:508-522
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om000722z
Popis:	Bis(alkylcyclopentadienyl)arenes have been prepared by sequential lithiation/alkylation of dibromoarenes with alkylcyclopenta-2-en-1-ones. The resulting dicarbinols were dehydrated with p-toluenesulfonic acid to give the bis(alkylcyclopentadienyl)arene. Poly(alkyl-1,1‘-ferrocenylenearylene)s were prepared by the reaction of dilithio bis(alkylcyclopentadienide)arenes and iron(II) salts in THF. The resulting polymers were oxidized with iodine to give the fully oxidized polyionomers. The polyionomers were found to give mixed-valence polymers when allowed to equilibrate with neutral polymers in solution, provided the degree of oxidation, N, lies between ca. 0.55 and 1.0. For degrees of oxidation 0.0 < N
Databáze:	OpenAIRE
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