Intercalation of van der Waals layered materials: A route towards engineering of electron correlation*

Autor: Xiaosong Wu, Jingjing Niu, Shulin Chen, Peng Gao, Dapeng Yu, Yanfeng Zhang, Dayu Yan, Zhilin Li, Sixian Yang, Youguo Shi, Wenjie Zhang, Xinguo Ren, Zhepeng Zhang
Rok vydání: 2020
Předmět:
Zdroj: Chinese Physics B. 29:097104
ISSN: 1674-1056
DOI: 10.1088/1674-1056/abab85
Popis: Being parent materials of two-dimensional (2D) crystals, van der Waals layered materials have received revived interest. In most 2D materials, the interaction between electrons is negligible. Introducing the interaction can give rise to a variety of exotic properties. Here, via intercalating a van der Waals layered compound VS2, we find evidence for electron correlation by extensive magnetic, thermal, electrical, and thermoelectric characterizations. The low temperature Sommerfeld coefficient is 64 mJ⋅K−2⋅mol−1 and the Kadowaki–Woods ratio r KW ∼ 0.20a 0. Both supports an enhancement of the electron correlation. The temperature dependences of the resistivity and thermopower indicate an important role played by the Kondo effect. The Kondo temperature T K is estimated to be around 8 K. Our results suggest intercalation as a potential means to engineer the electron correlation in van der Waals materials, as well as 2D materials.
Databáze: OpenAIRE