A General Protocol for Addressing Speciation of the Active Catalyst Applied to Ligand-Accelerated Enantioselective C(sp3)–H Bond Arylation

Autor:	James R. Gage, Jin-Quan Yu, David E. Hill, Qing-lan Pei, Donna G. Blackmond, En-xuan Zhang
Rok vydání:	2018
Předmět:	010405 organic chemistry Hydrogen bond Ligand Chemistry Enantioselective synthesis General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Catalytic cycle Genetic algorithm Surface modification
Zdroj:	ACS Catalysis. 8:1528-1531
ISSN:	2155-5435
Popis:	The potential role of dimeric catalyst species on or off the catalytic cycle is considered for a case of Pd-catalyzed C–H functionalization, leading to the development of a general experimental protocol that uses the reaction itself to report on the presence and role of dimeric species in asymmetric catalytic reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cef640c28c9e8160e13f983d99b00589 https://doi.org/10.1021/acscatal.8b00103 Zobrazit plný text záznamu