Autor:	I. I. Il'ina, Irina L. Simakova, V. A. Semikolenov
Rok vydání:	2002
Předmět:	Hydrogen Kinetics chemistry.chemical_element General Chemistry Heterogeneous catalysis Photochemistry Redox Heterolysis Catalysis Computer Science Applications Homolysis chemistry Modeling and Simulation Palladium
Zdroj:	Kinetics and Catalysis. 43:652-656
ISSN:	0023-1584
DOI:	10.1023/a:1020691626999
Popis:	The liquid-phase hydrogenation of pinane hydroperoxide (PHP) to pinanol on a Pd/C catalyst at 20–80°C and hydrogen pressures of 1–11 atm was studied. It was found that the rate of hydrogenation decreased with PHP concentration. The rate of PHP hydrogenation dramatically increased as the pressure of hydrogen was increased in a range of 2.5–3 atm. A mechanism was proposed for the hydrogenation of PHP. According to this mechanism, the step of hydrogen activation (homolytic or heterolytic addition) depends on the redox properties of the catalyst surface (the ratio between adsorbed PHP species and H2). It was found that pinanol can be prepared with high selectivity by the hydrogenation of PHP on a Pd/C catalyst under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cedefa87183cf69da314dbb36b157160 https://doi.org/10.1023/a:1020691626999 Zobrazit plný text záznamu Full text from SpringerLink