Characterizing the kinetics of free and bound water using a non-isothermal sorption technique
Autor: | E. H. Wong |
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Rok vydání: | 2016 |
Předmět: |
Arrhenius equation
Chemistry General Chemical Engineering Diffusion Kinetics Analytical chemistry Sorption 04 agricultural and veterinary sciences 02 engineering and technology 021001 nanoscience & nanotechnology Thermal diffusivity 040401 food science Isothermal process symbols.namesake 0404 agricultural biotechnology symbols Bound water Physical and Theoretical Chemistry 0210 nano-technology Dissolution |
Zdroj: | Drying Technology. 35:46-54 |
ISSN: | 1532-2300 0737-3937 |
DOI: | 10.1080/07373937.2016.1158722 |
Popis: | This article presents novel techniques for characterising the kinetics of the free and bound water in a specimen by performing only one single sorption experiment. By monitoring the time-variation of the residual water in a specimen that undergoes a controlled non-isothermal sorption over the range of temperatures of interest, the initial mass of the free and bound water in the specimen, the Arrhenius constants of diffusivity of the free water and the Arrhenius constants of the rate of dissolution of the bound water can be extracted through a combination of time-temperature transformation and regression. |
Databáze: | OpenAIRE |
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