Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes

Autor:	Teruo Shinmyozu, Hiroyuki Oku, Manami Yoshikawa, Kouta Sugahara, Hitoshi Tatemitsu, Shota Nakano, Hiroyuki Takemura, Tetsuo Iwanaga, Katsuya Sako, Michito Shiotsuka, Toshiaki Kakehi, Xu Feng Shen, Shinji Toyota
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Organic Chemistry chemistry.chemical_element Crystal structure Electrochemistry Biochemistry Ruthenium Bipyridine chemistry.chemical_compound chemistry Drug Discovery Polymer chemistry Organic chemistry Crown ether
Zdroj:	Tetrahedron Letters. 55:749-752
ISSN:	0040-4039
Popis:	Two novel redox-active 1,3-dithiole (DT) ring-fused 4,5-diazafluorene ligands with crown ether moieties (L1 and L2) were synthesized and characterized. The crystal structure of L1 was studied. The electrochemical and spectroscopic properties of these new ligands, as well as the corresponding bis(bipyridine)ruthenium(II) complexes [4: Ru L1(bpy)2 and 5: Ru L2(bpy)2], were also been investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ceb48c0a1315ccb11c267346548909e4 https://doi.org/10.1016/j.tetlet.2013.12.013 Zobrazit plný text záznamu Full Text from ScienceDirect